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Abstract The primary and secondary fragmentation dynamics of iodobenzene following its ionization at 120 eV were determined using three-dimensional velocity map imaging and covariance analysis. Site-selective iodine 4d ionization was used to populate a range of excited polycationic parent states, which primarily broke apart at the carbon-iodine bond to produce I⁺with phenyl or phenyl-like cations (C_nH ${{}_x}^{+}$or C_nH ${{}_x}^{2+}$, withn  =  1 – 6 andx  =  1 – 5). The molecular products were produced with varying degrees of internal excitation and dehydrogenation, leading to stable and unstable outcomes. This further allowed the secondary dynamics of ${\mathrm{C}}_6{\mathrm{H}}_x{}^{2+}$intermediates to be distinguished using native-frame covariance analysis, which isolated these processes in their own centre-of-mass reference frames. The mass resolution of the imaging mass spectrometer used for these measurements enabled the primary and secondary reaction channels to be specified at the level of individual hydrogen atoms, demonstrating the ability of covariance analysis to comprehensively measure the competing fragmentation channels of aryl cations, including those involving intermediate steps. 

Abstract Extreme precision radial velocity (EPRV) measurements contend with internal noise (instrumental systematics) and external noise (intrinsic stellar variability) on the road to 10 cm s⁻¹“exo-Earth” sensitivity. Both of these noise sources are well-probed using “Sun-as-a-star” RVs and cross-instrument comparisons. We built the Solar Calibrator (SoCal), an autonomous system that feeds stable, disk-integrated sunlight to the recently commissioned Keck Planet Finder (KPF) at the W. M. Keck Observatory. With SoCal, KPF acquires signal-to-noise ratio (S/N) ∼ 1200,R= 98,000 optical (445–870 nm) spectra of the Sun in 5 s exposures at unprecedented cadence for an EPRV facility using KPF’s fast readout mode (<16 s between exposures). Daily autonomous operation is achieved by defining an operations loop using state machine logic. Data affected by clouds are automatically flagged using a reliable quality control metric derived from simultaneous irradiance measurements. Comparing solar data across the growing global network of EPRV spectrographs with solar feeds will allow EPRV teams to disentangle internal and external noise sources and benchmark spectrograph performance. To facilitate this, all SoCal data products are immediately available to the public on the Keck Observatory Archive. We compared SoCal RVs to contemporaneous RVs from NEID, the only other immediately public EPRV solar data set. We find agreement at the 30–40 cm s⁻¹level on timescales of several hours, which is comparable to the combined photon-limited precision. Data from SoCal were also used to assess a detector problem and wavelength calibration inaccuracies associated with KPF during early operations. Long-term SoCal operations will collect upwards of 1000 solar spectra per six-hour day using KPF’s fast readout mode, enabling stellar activity studies at high S/N on our nearest solar-type star. 

Abstract We present optical spectroscopy of 710 solar neighborhood stars collected over 20 years to catalog chromospheric activity and search for stellar activity cycles. The California Legacy Survey stars are amenable to exoplanet detection using precise radial velocities, and we present their CaiiH and K time series as a proxy for stellar and chromospheric activity. Using the High Resolution Echelle Spectrometer at Keck Observatory, we measured stellar flux in the cores of the CaiiH and K lines to determineS-values on the Mount Wilson scale and the $\log \left(R_{\mathrm{HK}}^{\prime }\right)$metric, which is comparable across a wide range of spectral types. From the 710 stars, with 52,372 observations, 285 stars were sufficiently sampled to search for stellar activity cycles with periods of 2–25 yr, and 138 stars showed stellar cycles of varying length and amplitude.S-values can be used to mitigate stellar activity in the detection and characterization of exoplanets. We used them to probe stellar dynamos and to place the Sun's magnetic activity into context among solar neighborhood stars. Using precise stellar parameters and time-averaged activity measurements, we found tightly constrained cycle periods as a function of stellar temperature between $\log \left(R_{\mathrm{HK}}^{\prime }\right)$of −4.7 and −4.9, a range of activity in which nearly every star has a periodic cycle. These observations present the largest sample of spectroscopically determined stellar activity cycles to date. 

Abstract We present high-precision radial velocity observations of Gaia BH1, the nearest known black hole (BH). The system contains a solar-type G star orbiting a massive dark companion, which could be either a single BH or an inner BH + BH binary. A BH + BH binary is expected in some models where Gaia BH1 formed as a hierarchical triple, which is attractive because they avoid many of the difficulties associated with forming the system through isolated binary evolution. Our observations test the inner binary scenario. We have measured 115 precise RVs of the G star, including 40 from ESPRESSO with a precision of 3–5 m s⁻¹, and 75 from other instruments with a typical precision of 30–100 m s⁻¹. Our observations span 2.33 orbits of the G star and are concentrated near a periastron passage, when perturbations due to an inner binary would be largest. The RVs are well-fit by a Keplerian two-body orbit and show no convincing evidence of an inner binary. UsingREBOUNDsimulations of hierarchical triples with a range of inner periods, mass ratios, eccentricities, and orientations, we show that plausible inner binaries with periodsP_inner≳ 1.5 days would have produced larger deviations from a Keplerian orbit than observed. Binaries withP_inner≲ 1.5 days are consistent with the data, but these would merge within a Hubble time and would thus imply fine-tuning. We present updated parameters of Gaia BH1's orbit. The RVs yield a spectroscopic mass function $f\left(M_{\mathrm{BH}}\right)=3.9358\pm 0.0002M_{\odot }$—about 7000σabove the ∼2.5M_⊙maximum neutron star mass. Including the inclination constraint from Gaia astrometry, this implies a BH mass ofM_BH= 9.27 ± 0.10M_⊙. 

Abstract The discovery and characterization of extrasolar planets using radial velocity (RV) measurements is limited by noise sources from the surfaces of host stars. Current techniques to suppress stellar magnetic activity rely on decorrelation using an activity indicator (e.g., strength of the Ca ii lines, width of the cross-correlation function, broadband photometry) or measurement of the RVs using only a subset of spectral lines that have been shown to be insensitive to activity. Here, we combine the above techniques by constructing a high-signal-to-noise activity indicator, the depth metric  ( t ) , from the most activity-sensitive spectral lines using the “line-by-line” method of Dumusque (2018). Analogous to photometric decorrelation of RVs or Gaussian progress regression modeling of activity indices, time series modeling of  ( t ) reduces the amplitude of magnetic activity in RV measurements; in an α CenB RV time series from HARPS, the RV rms was reduced from 2.67 to 1.02 m s −1 .  ( t ) modeling enabled us to characterize injected planetary signals as small as 1 m s −1 . In terms of noise reduction and injected signal recovery,  ( t ) modeling outperforms activity mitigation via the selection of activity-insensitive spectral lines. For Sun-like stars with activity signals on the m s −1 level, the depth metric independently tracks rotationally modulated and multiyear stellar activity with a level of quality similar to that of the FWHM of the CCF and log R HK ′ . The depth metric and its elaborations will be a powerful tool in the mitigation of stellar magnetic activity, particularly as a means of connecting stellar activity to physical processes within host stars. 

As part of the Keck Planet Finder (KPF) project, a Fiber Injection Unit (FIU) was implemented and will be deployed on the Keck Ⅰ telescope, with the aim of providing dispersion compensated and tip/tilt corrected light to the KPF instrument and accompanying H&K spectrometer. The goal of KPF is to characterize exoplanets via the radial velocity technique, with a single measurement precision of 30cm/s or better. To accomplish this, the FIU must provide a stable F-number and chief ray angle to the Science and Calcium H&K fibers. Our design approach was use a planar optical layout with atmospheric dispersion compensation for both the Science and Calcium H&K arms. A SWIR guider camera and piezo tip/tilt mirror are used to keep the target centered on the fibers. 

Abstract Filming atomic motion within molecules is an active pursuit of molecular physics and quantum chemistry. A promising method is laser-induced Coulomb Explosion Imaging (CEI) where a laser pulse rapidly ionizes many electrons from a molecule, causing the remaining ions to undergo Coulomb repulsion. The ion momenta are used to reconstruct the molecular geometry which is tracked over time (i.e., filmed) by ionizing at an adjustable delay with respect to the start of interatomic motion. Results are distorted, however, by ultrafast motion during the ionizing pulse. We studied this effect in water and filmed the rapid “slingshot” motion that enhances ionization and distorts CEI results. Our investigation uncovered both the geometry and mechanism of the enhancement which may inform CEI experiments in many other polyatomic molecules.